Abstract

Each spin-multiplet of a spectrum obtained from a secondary radical, created by reaction of a radical pair mechanism-polarized primary radical, may show local multiplet polarization if a hyperfine coupling is correlated between the two. The recent results of Sakaguchi, Hayashi, Murai and l'Haya are discussed in this light. The relative signs of the correlated hyperfine coupling constants in the two radicals can be obtained.

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