Olive oil residue gasification and syngas integrated clean up system

Abstract

Gasification is one of the most promising technologies to convert low quality fuels into more valuable ones. The main problem in the use of biomass in gasification processes is the high amount of tar released in the pyrolysis step. It is thus necessary to recover the tar and to transform it in lighter combustible gas species such as CH4, CO and H2 by means of catalytic processes. In this work the gasification of olive husk is performed in order to produce a high quality syngas, composed mainly of carbon monoxide and hydrogen, using an innovative laboratory scale plant composed of a unique reactor divided into three sections. The first section is dedicated to the pyrolysis, the second to the gasification of char produced during pyrolysis and the third to the catalytic reforming of tar. In the reformer two catalysts were tested: a CeO2 promoted bimetallic Ni–Co catalyst and a Ni catalyst, both supported on γ-Al2O3. This plant design allows one to minimize the heat dispersion enhancing the energy efficiency of the unit.