Olive Oil Mill Wastewater for Remediation of Slag Contaminated Soil

Abstract

Two olive mill wastewaters (OMW) samples, OMWa and OMWb, containing different polyphenolic loads were used for decontaminating an unauthorized dump site in the Campania region, south Italy. In a bench-scale experiment, OMWa at pH 6.0 (OMWapH6.0) and 4.7 (OMWapH4.7), OMWb at pH 4.7 (OMWbpH4.7) and OMWa free of the polyphenolic moiety polyphenol-free OMWa (PF-OMWa) were added to the soil for a 96h contact time. At 96h, OMWapH4.7 was more effective than OMWapH6.0, with Cd, Cu, Pb and Zn removal percentages of 30.7-68.1. Cd and Pb levels were 6.0 and 915mgkg(-1), respectively, decreasing below the regulatory limits for industrial and commercial areas (15.0 and 1×10(3) mgkg(-1), respectively). A threefold decrease in Zn levels was also observed from 13.5×10(3) to 4.3×10(3)mgkg(-1). The metal removal efficiency of PF-OMWa dropped from 30.7% to 15.6% for Cd and from 37.9% to 1.3% for Pb. OMWbpH4.7 at 96h was more efficient than OMWapH4.7, with mean removal percentages of 32.5 versus 7.8, respectively.