Olive Mill Wastewater: From a Pollutant to Green Fuels, Agricultural Water Source and Bio-Fertilizer—Part 1. The Drying Kinetics

Abstract

Olive Mill Wastewater (OMWW) treatment is considered to be one of the main challenges that Mediterranean countries face. Although several procedures and technologies are mentioned in the literature, these techniques have several disadvantages or have been limited to laboratory pilot validation without posterior industrial projection. Recently, an advanced environmental friendly strategy for the recovery of OMWW was established involving the impregnation of OMWW on dry biomasses, drying of these impregnated samples, and finally green fuels and biochar production. This established strategy revealed that the drying step is crucial for the success of the entire recovery process. Hence, two impregnated samples were prepared through OMWW impregnation on sawdust (IS) and olive mill solid waste (ISW). The drying kinetics of OMWW and impregnated samples (IS and ISW) were examined in a convective dryer (air velocity range from 0.7–1.3 m/s and the temperature from 40–60 °C). The experimental results indicated that the drying of the impregnated samples occurred twice as fast as for the OMWW sample. Such behavior was attributed to the remaining thin layer of oil on the OMWW surface Furthermore, the Henderson and Pabis model showed the suitable fit of the drying curves with a determination coefficient R2 above 0.97. The drying rates were extracted from the mathematical models and the drying process was analyzed. The coefficient of effective diffusivity varied between 2.8 and 11.7 × 10−10 m2/s. In addition, the activation energy values ranged between 28.7 and 44.9 kJ/mol. These values were in the same range as those obtained during the drying of other agrifood byproducts. The final results could be very helpful to engineers aiming to improve and optimize the OMWW drying process.