Olive mill wastewater from a liquid biological waste to a carbon/oxocalcium composite for selective and efficient removal of methylene blue and paracetamol from aqueous solution

Abstract

In this study, a Carbon/Oxocalcium was prepared from olive mill wastewater and successfully applied to the removal of paracetamol and methylene blue (MB) from an aqueous medium. The optimized composite (0.3 % CaO) is rich in anionic sites, porous and has a specific surface area of about 1383 m2.g−1. Adsorption tests showed significant adsorption capacities up to 1141 mg.g−1. The adsorption of MB and paracetamol is well described by the Redlich-Peterson and Dubinin-Radushkevich isotherm, respectively. Moreover, the adsorption kinetics fitted to pseudo-second order. The π -π interactions, hydrogen bonds and electrostatic interactions were responsible for the adsorption of paracetamol and MB substrates. This work develops by a single, easy and simple action a new effective and selective material for the removal of emerging pollutants, a new method for the development of more stable carbon composites and a cost-effective method for the valorization of olive mill wastewater.