Abstract
Illuminating quadruple bonds: The polymeric materials [M2(O2CC6H2-2,4,6-Me3)2(O2C-(Thp)n-CO2)]n (M=Mo or W (green); Thp=thiophene (S atoms yellow); DMSO molecules also shown) incorporate metal–metal quadruple bonds and form thin films from THF solutions. These films show electroluminescence when deposited on an indium–tin oxide glass-coated plate followed by vapor deposition of aluminum or calcium.
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