Abstract

AbstractThe concept for a new class of nonplanar polyaromatic hydrocarbons — the funnelenes — is presented. Retrosynthetic considerations lead to polyphenyl‐ and oligophenylcalix[4]arenes as potential precursors. In this paper we describe the synthesis of these calixarenes and the first cyclodehydration studies on a model compound which leads to a hexabenzocoronene derivative. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

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