Abstract
Oligomerization of pent-1-ene is an effective process for synthesis of high-quality environmentally friendly fuel components. Catalytic properties of H-zeolites FAU, OFF, MOR, ВЕА, MTW and MFI were studied for synthesis of pentene oligomers in an autoclave at 110–200 °C. The wide-pore structure of H-Y and H-Beta (18) zeolites and the high concentration of acid sites were established to cause the high oligomerization activity to obtain 97–100 % yields of oligomers. Oligomers obtained over these catalysts comprised, depending on the reaction conditions, 30–73 % dimers, 25–50 % trimers and 2–14 % oligomers with more than three monomer units (n > 3). Fine-pore zeolites (H-ZSM-5) and zeolites with one-dimensional channel systems (H-OFF, H-MOR, H-ZSM-12) were less active to oligomerization of pent-1-ene, decenes being the main reaction products.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
