Abstract
AbstractKinetics of addition of ethylene oxide to the POH groups in phosphorous (H3PO3) and phosphoric acid (H3PO4) were studied. The reaction is catalysed by the POH groups themselves, presumably by formation of hydrogen‐bonded complexes with ethylene oxide. The values of apparent rate constants of reactions involving subsequent POH groups were determined. The apparent reactivity of POH increases with increasing number of OCH2CH2OH substituents present in the reacting molecule. This has been attributed to the formation of intramolecular hydrogen bonds influencing the reactivity of the POH groups. Mechanistic implications and the distribution of products are discussed in connection with the observed kinetic dependences.
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