Abstract
Abstract Poly(phenazine-2,7-diyl), P(2,7-Phzn), a new π -conjugated polymer constituted of highly electron-accepting phenazine units, has been prepared by dehalogenation polymerization of 2,7-dibromophenazine. The polymer undergoes electrochemical reduction with E p of −1.46 V versus Ag ∣ Ag + , and the potential is the highest amongst reported reduction potentials of poly(arylene)s. Oligomeric poly(thianthrene-2,7-diyl), an analogue of P(2,7-Phzn), is also electrochemically active.
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