Abstract
The syntheses, structures and luminescent properties of two unusual mixed-metal coordination polymers, namely [Ag 4Cd 2(tren) 2(CN) 7.5][Ag(CN) 1.5] 1 and [Au 2Cd(tren)(CN) 4]·H 2O 2 (tren = tris(2-aminoethyl)amine), are presented. Both compounds contain abnormal metal cords of oligocyanometallic anions as building blocks wherein the d 10–d 10 interaction plays a crucial role in the metal–metal assembly.
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