Oleic acid-modified layered double hydroxide for Pickering emulsions: (I) Interfacial properties

Abstract

Layered double hydroxides (LDHs) are one type of potential emulsifiers for Pickering emulsions. Surface modification can regulate their surface properties, thereby affecting their emulsifying behavior. However, there is still a lack of full understanding of the impact of surface modification on their surface properties. In the current work, one Mg3Al-Cl LDH was modified using oleic acid (OA), obtaining six OA-modified products with different OA loadings. Their contact angles and relative dielectric constants were determined, and their surface properties including the interfacial free energies (γ) and solubility parameters (δ) were then estimated from the data. Their apparent molar volumes were estimated using the γ and δ data. OA molecules are coated on the LDH surface via the bidentate bonding mode to form monolayers. The OA modification has no obvious impact on the structure and morphology of LDH particles, but can significantly affect their surface properties. This work provides a better understanding of the dependence of surface properties of LDHs on the surface modification.