Abstract
The metathesis of methyl oleate with the WCl6-cocatalyst system was investigated. Tetra-n-butyl-stannane, tetraethylstannane and triethylaluminum were effective as cocatalysts. The optimum reaction condition was considerably different from that for the metathesis of internal alkene having no functional group. The addition of methyl oleate or methyl stearate depressed the various side reactions in the metathesis of alkenes having no functional group. These facts indicate that in spite of the high reaction temperature, the relatively high selectivity is obtained in the metathesis of methyl oleate owing to the existence of its ester group. Cross metathesis of methyl oleate and 1-decene was examined.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
