Abstract

Superconductor-ferromagnetic heterostructures have been suggested as one of the most promising alternatives of realizing odd-frequency superconductivity. In this work we consider the limit of shrinking the ferromagnetic region to the limit of a single impurity embedded in a conventional superconductor, which gives raise to localized Yu-Shiba-Rusinov (YSR) bound states with energies inside the superconducting gap. We demonstrate that all the sufficient ingredients for generating odd-frequency pairing are present at the vicinity of these impurities. We investigate the appearance of all possible pair amplitudes in accordance with the Berezinskii $SP^{\ast}OT^{\ast} = -1$ rule, being the symmetry under the exchange of spin, spatial, orbital (in our case $O=+1$) and time index, respectively. We study the spatial and frequency dependence of of the possible pairing amplitudes, analyzing their evolution with impurity strength and identifying a reciprocity between different symmetries related through impurity scattering. We show that the odd-frequency spin-triplet pairing amplitude dominates at the critical impurity strength, where the YSR states merge at the middle of the gap, while the even components cancel out close to the impurity. We also show that the spin-polarized local density of states exhibits the same spatial and frequency behavior as the odd-$\omega$ spin-triplet component at the critical impurity strength.

Highlights

  • Odd-frequency superconducting (SC) pairing is a proposed unconventional dynamic SC state that is both nonlocal and odd in the relative time coordinate [1]

  • It has been shown that phonon-mediated electron-electron interactions cannot stabilize an odd-ω SC order parameter (OP) [7], but other mechanisms based on spin-fluctuation-mediated interactions

  • We have demonstrated that the YSR bound states formed at the vicinity of magnetic impurities in conventional superconductors harbor spin-triplet, odd-ω pair correlations, which may be referred to as Berezinskii-YSR (BYSR) states

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Summary

INTRODUCTION

Odd-frequency (odd-ω) superconducting (SC) pairing is a proposed unconventional dynamic SC state that is both nonlocal and odd in the relative time coordinate [1]. A different approach to inducing odd-ω pair correlations is through engineering heterostructures where a conventional (even-frequency, spin-singlet, s-wave) SC is proximitized to region that causes the breaking of some of its symmetries This generates a corresponding odd-ω correlation component These magnetic impurities were instrumental in mapping out the spatial symmetry of the order parameter through scanning tunneling spectroscopic measurements in the cuprate superconductors [27]. Analytic expressions and derivation details are given in the Appendices

MODEL AND METHOD
Analytic expression for the impurity Green’s function
Reciprocal relations between singlet and triplet pair correlations
Spin-polarized local density of states
Local pair correlations spectra
Nonlocal pair correlations spectra
CONCLUSIONS
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