Octahydropyrrolo[4,3,2-m,n]acridine derivatives. 2. 1-Aryl-4,4,8,8-tetramethyl-2,3,4,5,7,8,9,10-octahydropyrrolo[4,3,2-m,n]-acridin-10-ones and intermediates in their synthesis

E A Bisenieks,Ya R Uldrikis,G Ya Dubur,N V Makarova

doi:10.1007/bf00478862

Octahydropyrrolo[4,3,2-m,n]acridine derivatives. 2. 1-Aryl-4,4,8,8-tetramethyl-2,3,4,5,7,8,9,10-octahydropyrrolo[4,3,2-m,n]-acridin-10-ones and intermediates in their synthesis

E A Bisenieks, Ya R Uldrikis + Show 2 more

https://doi.org/10.1007/bf00478862

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Journal: Chemistry of Heterocyclic Compounds	Publication Date: Apr 1, 1988
Citations: 7

Affiliation: Latvian Academy of Sciences, Institute of Organic Synthesis

#Tetrahydroindole Derivatives #Intermediate Formation

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Abstract

A series of 9-aroyl-3,3,6,6-tetramethyl-1,2,3,4,5,6,7,8-octahydroxanthen-1,8-diones has been prepared from arylglyoxals and dimedone in a dehydrating medium; upon heating with ammonia these compounds are converted to 1-aryl-4,4,8,8-tetramethyl-2,3,4,5,7,8,9,10-octahydropyrrolo[4,3,2-m,n]acridin-10-ones. These reactions occur via the intermediate formation of tetrahydroindole derivatives.

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