Abstract
A new fluorescent hybrid porous polymer (HPP) is synthesized by an anhydrous FeCl3 -mediated oxidative coupling reaction of octa[4-(9-carbazolyl)phenyl]silsesquioxane (OCPS). The polymer possesses a surface area of 1741 m2 g-1 and hierarchical bimodal micropores (1.41 and 1.69 nm) and mesopores (2.65 nm). The material serves as an excellent adsorbent for CO2 and dyes with high adsorption capacity for CO2 (8.53 wt %,1.94 mmol g-1 ), congo red (1715 mg g-1 ) and rhodamine B (1501 mg g-1 ). In addition, the presence of peripheral cabozolyl groups with extended π-conjugation in the crosslinked framework imparts luminescent character to the polymer and offers the detection of nitroaromatic compounds.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
