Occurrence, risk and influencing factors of polycyclic aromatic hydrocarbons in surface soils from a large-scale coal mine, Huainan, China.

Abstract

Coal is one of the most important fossil fuels for energy, but it can cause serious polycyclic aromatic hydrocarbon (PAH) pollution to the environment. In this work, the distribution, sources, influencing factors, and risk assessment of PAHs were studied in a soil of typical coal resource city, Huainan, China. The total concentration of 16 PAHs classified by USEPA in 47 soils ranged from 109.94 to 1105.30ng/g with a mean concentration of 528.06ng/g. The PAH concentration was higher in soil of this area than most of the agricultural, urban and industrial soils and lower than some coal mine and coal-fired power plant areas in the world. The principal component analysis (PCA) and diagnostic ratios demonstrated that PAHs in soils were mainly from the coal combustion and refined petroleum products. The total organic carbon (TOC, p<0.01) and black carbon (BC, p<0.01) can significantly influence PAH inventories in soils, particularly for PAHs with high molecular weight. In addition, the significantly positive correlations between PAHs in feed coal (p<0.05), fly ash (p<0.01), particulate matter (PM1-2.5 and PM2.5-10, p<0.01) and PAHs in soils revealed that the emission sources and deposition processes were also the main factors affecting PAH contents in soils. The estimated values of incremental lifetime cancer risk (ILCR) for children and adults were higher than 10-4at all sampling sites, suggesting high carcinogenic risks for local residents, and the most important exposure route for PAHs was dermal absorption. These findings are valuable for assessing the health risk of PAHs in soils around typical coal mine and coal-fired power plants and highlight the urgency of taking actions to control and reduce the carcinogenic risks for local residents.