Occurrence of organic micropollutants and heavy metals in the soil after the application of stabilized sewage sludge.

Abstract

Stabilized sewage sludge could be used as a fertilizer in the soil because of nitrogen, phosphorus, and other micronutrition material to improve the properties of the soil. In this study, clover and fodder corn plants were planted in the soil to which stabilized sewage sludge was applied. The soil was analyzed and evaluated by collecting samples to determine changes in the application fields before plantation and one year after the harvest. To monitor changes in the soil and after the application of stabilized sludge to the soil, the stabilized sewage sludge was evaluated for the suitability of parameters such as heavy metals, halogenated organic compounds including adsorbable organic halogens (AOX), nonylphenol ethoxylates (NPE), polycyclic aromatic hydrocarbon compounds (PAH), polychlorinated biphenyls (PCB), di(2-ethylhexyl) phthalate (DEHP), linear alkylbenzene sulphonates (LAS), polychlorinated dibenzo-p-dioxins and dibenzo-p-furans (PCDD/F), and pathogens and other parameters containing organic matter (OM), pH, conductivity (EC), total nitrogen (TN), and total phosphorus (TP). After the sludge application, the heavy metal content increased, except for Zn. The application of stabilized sludge as a soil conditioner and humus caused a significant increase in the TN and TP content since the product increased the harvest that increased soil nutrition. After the sludge application to the soil, the concentration of organic micropollutants in the soil did not change. The concentration of AOX and PCDD/F in the soil increased by 141% and 125%, respectively.