Occurrence and distribution of organochlorine pesticides and polycyclic aromatic hydrocarbons in surface sediments from Qinghai Lake, northeast Qinghai–Tibet plateau, China

Abstract

Organochlorine pesticides (OCPs) and polycyclic aromiatic hydrocarbons (PAHs) were analyzed in surface sediment samples collected from Qinghai Lake, the largest lake in China, which is situated in the northeast Qinghai–Tibet plateau at an altitude of 3200m. The concentrations of these pollutants ranged from 0.02 to 1.00ng/g for hexachlorocyclohexanes (HCHs), from not detected to 0.86ng/g for dichlorodiphenyltrichloroethanes (DDTs), from 0.26 to 1.73ng/g for OCPs, and from 366 to 966ng/g for PAHs. The predominance of α-HCH suggests that long-range atmospheric transport is an important source for HCHs. A low α- to γ-HCH ratio (3.87 on average) indicates the possible usage of lindane in the drainage basin. The high percentage of p,p′-DDE and p,p′-DDD and the low percentage of o,p′-DDT indicated significant degradation from previous inputs, and no recent inputs of dicofol derived DDT. Based on the analysis of the component ratios, PAHs were found to be primarily from the combustion of biomass and coal-based fossil fuels. Using the Canadian sediment guidelines, PAHs are of greater ecological concern than OCPs in Qinghai Lake.