Abstract
Some dithiocarbamato-bridged heterobimetallic complexes [M′{M(S 2CNR 2) 3} 2] and [{M′M(S 2CNR 2) 4} n ], obtained by successive addition of stoichiometric amounts of bivalent metal salts MX 2 (M = Zn, Cd or Hg) and M′Y 2 (M′ = VO, Mn, Fe, Co, Ni, Cu or Zn) to a solution of a sodium dithiocarbamate, are reformulated as mixtures of homonuclear complexes involving, in some instances (M′ = Mn, Fe or Co), trivalent [M′(S 2CNR 2) 3] species.
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