Abstract
Photoelectron measurements on transition metal carbonyls in the gas phase were made at various photon energies. Satellite peaks on the low kinetic energy side of the valence orbitals are observed and are attributed to shake up of the CO derived levels. The variation of the intensity of the shake up, relative to the main peak with the kinetic energy at which the shake up peaks are observed, provides evidence for time dependent relaxation of the final state. This data indicates that the shake up intensity is constant for kinetic energies greater than ≈20 eV.
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