Abstract
Fluorescence of trans-stilbene in ethane at 350 K gives the barrier crossing rates as a function of pressure in the range 0 to 170 atm. The data demonstrate a peak in the rate at 120 atm (a collision frequency of (6–7)×10 12 s −1, or a viscosity of 0.03 cP). The data are discussed in terms of the dimensionality; clustering near the critical pressure; collisional deactivation; and local field effects.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
