Abstract

The optical response of high quality three dimensionally (3D) ordered photonic crystals is analyzed in the high energy region. By tuning the reflectance with the angle of incidence of light, the peaks in the reflection spectrum that correspond to the first, second, and third order photonic stop bands and the van Hove singular point in the photon density of states are clearly distinguished. The high energy features have been observed for photonic crystals made from colloids of different diameters, having different index contrast and fabricated by two different self-assembly routes. The observation of van Hove singularity at near-normal incidence of light and its presence even in low index-contrast photonic crystals provide conclusive evidence that these high energy features are due to the perfect periodic ordering present in the photonic crystals with less defects and disorder.

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