Observation of high enantioselectivity for the gas phase hydrogenation of methyl pyruvate using supported Pt catalysts pre-modified with cinchonidineElectronic supplementary information (ESI) available: use of the Kelvin equation and reactant partial pressure to estimate the effective partial pressure for condensation as a function of pore radius. See http://www.rsc.org/suppdata/cc/b3/b304976k/

Matthias Von Arx,Nicholas Dummer,Richard P K Wells,Stuart H Taylor,David J Willock,Graham J Hutchings,Peter B Wells

doi:10.1039/b304976k

Observation of high enantioselectivity for the gas phase hydrogenation of methyl pyruvate using supported Pt catalysts pre-modified with cinchonidineElectronic supplementary information (ESI) available: use of the Kelvin equation and reactant partial pressure to estimate the effective partial pressure for condensation as a function of pore radius. See http://www.rsc.org/suppdata/cc/b3/b304976k/

Matthias Von Arx, Nicholas Dummer + Show 5 more

https://doi.org/10.1039/b304976k

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Journal: Chemical Communications	Publication Date: Jan 1, 2003
Citations: 25

Affiliation: Cardiff University, University of Aberdeen, University of Basel

#Hydrogenation Of Methyl Pyruvate #Function Of Pore Radius + Show 8 more

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Abstract

Pt supported on alpha-Al2O3, gamma-Al2O3 and SiO2 pre-modified with cinchonidine gives over 50% ee in the hydrogenation of methyl pyruvate to methyl lactate using gas phase reactants at 40 degrees C giving the first clear observation of high enantioselection at the gas/solid interface.

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