Observation of Fano line shape in directional fluorescence emission mediated by coupled planar waveguide modes and interpretation based on Lorentz reciprocity

Byungjun Kang,Dmitry V Nesterenko,Kengo Motokura,Shinji Hayashi,Zouheir Sekkat,Minoru Fujii

doi:10.1063/5.0010930

Abstract

Using a reverse attenuated-total-reflection geometry, we measured angle-scan fluorescence emission spectra of all-dielectric multilayer samples containing a waveguide layer doped with fluorescent dye molecules (fluorescent waveguide layer). A sample containing only one fluorescent waveguide layer showed a highly directional emission spectrum with a Lorentzian line shape caused by the radiative decay of an excited planar waveguide mode into a traveling wave in a decoupling prism. Addition of another waveguide layer containing absorptive dye molecules was found to greatly modify the spectrum and generate a Fano line shape in the emission spectrum. The observed Lorentzian and Fano emission spectra could be well reproduced by electromagnetic calculations based on the Lorentz reciprocity theorem. Calculated results of electric field distributions indicate that the Fano line shape is generated by the suppression of local electric fields inside the fluorescent waveguide layer resulting from coupling between two waveguide modes.

Highlights

A sample containing only one fluorescent waveguide layer showed a highly directional emission spectrum with a Lorentzian line shape caused by the radiative decay of an excited planar waveguide mode into a traveling wave in a decoupling prism
Calculated results of electric field distributions indicate that the Fano line shape is generated by the suppression of local electric fields inside the fluorescent waveguide layer resulting from coupling between two waveguide modes
We see that the DCM-PS layer exhibits a broad absorption band peaking around λ = 470 nm with a full width at half maximum of ∼100 nm and a broad fluorescence band peaking around λ = 600 nm with a full width at half maximum of ∼115 nm

Summary

Introduction

A sample containing only one fluorescent waveguide layer showed a highly directional emission spectrum with a Lorentzian line shape caused by the radiative decay of an excited planar waveguide mode into a traveling wave in a decoupling prism. We used a reverse ATR geometry very similar to that used for observing surface plasmon-coupled emission.4–6 In the present geometry, the emission line shape reflects the Fano-resonant behavior of local electric fields inside the fluorescent waveguide layer.

Results

Conclusion