Abstract
In this paper rare gas fluoride ionic excimers, Ar<SUP>2+</SUP>F<SUP>-</SUP> and Kr<SUP>2+</SUP>F<SUP>-</SUP>, are studied theoretically and experimentally as candidates of VUV/XUV laser media. First, potential curves of rare gas fluoride ionic excimers were calculated with the aid of the improved Rittner potential which involved parameters corrected by ab initio calculation. Transition parameters of ionic excimers were also obtained. Then radiations from Ar<SUP>2+</SUP>F<SUP>-</SUP> near 125 nm and Kr<SUP>2+</SUP>F<SUP>-</SUP> near 148 nm were obtained for the first time, these results are in good agreement with our calculations.
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