Abstract
The ionization energy of SO3 is determined to be 12.828±0.010 eV from photoionization mass spectrometric measurements of SO3. Two autoionization Rydberg series converging to the SO3(2E′) state (17.901 eV) are identified. Three window resonances observed in the region 610–690 Å are assigned as members of an autoionizing Rydberg series converging to the SO+3(2A1) state (20.603 eV).
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