Observation and modeling of bound-free transitions to the X1Σ+ and a3Σ+ states of KCs

Abstract

The oscillation continuum in laser-induced fluorescence spectra of bound-free c3Σ+ → a3Σ+ and (4)1Σ+ → X1Σ+ transitions of the KCs molecule was recorded by a Fourier-transform spectrometer and modeled under the adiabatic approximation. The required interatomic potentials for ground a3Σ+ and X1Σ+ states were reconstructed in an analytical Chebyshev-polynomial-expansion form in the framework of the regularization direct-potential-fit procedure based on the simultaneous consideration of experimental line positions from Ferber et al. [Phys. Rev. A 80, 062501 (2009)] and the present ab initio calculation of short-range repulsive potential data. It was proved that the repulsive part over the dissociation limit of the derived a3Σ+ potential reproduces the experiment better than the potentials reported in the literature. It is also shown that all empirical and semi-empirical potentials available for the X1Σ+ state reproduce the bound-free (4)1Σ+ → X1Σ+ spectrum with equal quality in the range of observations.