Abstract

We observed for the first time an excimer emission of anthracene included in the supercages of zeolite X at high ratios of anthracene to supercage. The mechanism giving rise to the excimer emission was ascribed to charge recombination of anthracene cation—anion radical pair on the basis of picosecond time-resolved diffuse reflectance transient absorption studies as well as picosecond fluorescence measurements.

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