Abstract
The CD—Ar van der Waals complex has been generated in the gas phase by the 248 nm photolysis of CDBr3 entrained in a supersonic jet of argon. Rotationally resolved spectra associated with the complex have been observed by laser-induced fluorescence in the vicinity of the CD B 2Σ−-X 2Π (1, 0) band near 366 nm. Bands at 27310.7 and 27327.8 cm−1 are rotationally analyzed using computer simulations, and assigned as (1, 00, 0) and (1, 1p, 0), respectively. The vibronic structure of the CD—Ar excited states has also been analyzed using a model based on hindered internal rotation. The results are compared to those reported for CH—Ar.
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