Nutrients recovery from urine through struvite formation using lab-scale fluidized-bed homogeneous crystallization reactor

Abstract

Phosphorus (P) is considered the most important micro-element needed for every living thing. Even though they have limited amount, P and nitrogen (N) are responsible for eutrophication in water bodies. This paper aimed to give an insight into the removal efficiency of nutrients and struvite crystallization of slowly soluble fertilizer MgNH4PO4.6H2O, which is also called NH4+-struvite. Besides, using fluidized bed homogeneous crystallization (FBHC) system can reduce impurities in granular struvite generated during the reaction as the advantage function itself. The results showed the changes in pH, magnesium (Mg2+), phosphate (PO43--P), ammonium (NH4+-N), and appearance of spontaneous struvite precipitation over time. Using synthesis urine sample with adjusted pH and Mg2+ concentration to determine the optimal conditions for granular NH4+-struvite recovery to maintain Mg and P removal efficiency up to 99% in steady state. In this study, the removal efficiency of N was about 80 – 85% maximum. The initial results indicated the feasibility of simultaneous crystallizing NH4+-struvite which is mentioned above. It could easily form at pH around 8 – 9. On the other hand, urea hydrolysis makes a pH increase in urine from 6.5 to less than 9.0 at room temperature. This might cause a heavy impact on the NH4+-N crystallization during the formation of granular struvite if there has no suitable NH4+-N pretreatment options. For Mg recovery, the concentration of Mg is detrimental in the creation of struvite. This will bring better removal efficiency if there is an available Mg source in nature which can be reused directly in an environmentally eco-friendly way. The total mass of struvite precipitate obtained in the form of nuclei corresponds to 200 g/m3 of urine during 24 days operation.