Abstract

Abstract Wastewater management poses major environmental and economic problems in many small island developing states (SIDs), such as Trinidad and Tobago. Conventional wastewater treatment using activated carbon (AC) from charcoal is very costly. However, using spent coconut husks can be a cheap, environmentally friendly alternative source of AC for removing nitrogen and phosphorus in the secondary effluent. This study considered thermal and non-thermal, chemical activation methods to create four different AC treatments. The treatments considered included: virgin AC (thermally activated only) and subsequent acid treatments. Acid treatments were considered as an acidic environment, optimized nitrate and phosphate removal and reduced hydroxyl ion competition. Although all treatments effectively removed nitrates, virgin AC was ineffective in PO43−-P removal when concentrations were less than 10 mg/L. This was probably due to naturally occurring PO43−-P leaching from the coconut husk. The differences in removal efficiencies and adsorption capacities were not significantly different between treatments. Thermal activation was sufficient to remove NO3−-N and PO43−-P greater than 10 mg/L in experiments with batch stock solutions and the secondary effluent. Virgin AC can therefore be used as a potential substitute for conventional AC.

Highlights

  • Centralized wastewater treatment systems usually have high start-up and operational costs

  • NO3À-N removal in all treatments ranged between 74.0% and 90.3%, whereas PO43À-P removal efficiencies had a greater range between À9.9% and 80.8% (Figure 2)

  • The activated carbon (AC) treatments were successful in removing PO43À-P from the wastewater treatment plants (WWTPs) secondary effluent, with a mean removal efficiency of 57.9% and an effluent of 2.9 mg/L achieved

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Summary

Introduction

Centralized wastewater treatment systems usually have high start-up and operational costs. Most operational wastewater treatment plants (WWTPs) in small island developing states (SIDs), such as Trinidad and Tobago, utilize preliminary and primary sedimentation treatments. The effluent from these WWTPs is still nitrogen- and phosphorus-enriched. More attention has been placed on water conservation, reuse and advanced treatment technology that can increase operational costs. Some of these costs can be circumvented by using cheaper alternatives such as agricultural waste products to make sorbents, such as activated carbon (AC). This approach seems logical when trying to tackle solid waste and wastewater problems in SIDs

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