Abstract

PurposeMembrane filtration is recently applied to recover nutrients and dischargeable water from anaerobic sludge. The purpose of this study is to quantify nutrient separation, membrane performance, and process stability and to increase the economical applicability of the process by energetic optimisation.MethodsAt the site of a 2.5 MWe agricultural biogas plant, a membrane pilot plant was operated over a period of 7 months. It consisted of a screw press separator, a decanter centrifuge, an ultrafiltration unit, and a three-stage reverse osmosis unit. Mass and nutrient balances were generated by sampling and analysing every process stream. Process performance was analysed by monitoring separation efficiencies, membrane flux, cleaning intervals, and energy demand.ResultsSolid/liquid separation resulted in separation efficiencies of 70% for total solids and 80% for phosphorus. The solid fraction contained high concentrations of organics and particle-ligated nutrients (20% TS, 8 kg t−1 Ntotal, 5.5 kg t−1 P2O5). The retentate of the reverse osmosis had high concentrations of dissolved ammonia and potassium (4 kg t−1 NH4–N and 10 kg t−1 K2O). 38% of the sludge volume was recovered as clean water.ConclusionThe membrane pilot plant successfully produced a solid N/P-fertiliser, a liquid N/K-fertiliser and clean water. The results contribute to a sound understanding and growing database for future adaption of the process chain. Hydrodynamic optimisation within the pilot plant reduced the energy demand of the ultrafiltration step by 50%, which considerably contributes to the economy of the process.

Highlights

  • As a result of the German Renewable Energies Act, enacted in 2000, the number and size of biogas plants in Germany has constantly increased

  • Solid fractions were of dark brown colour, paste-like, and fibrous

  • The performed experimental tests demonstrate the successful separation of anaerobic sludge from an agricultural biogas plant over a 7-months operation period

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Summary

Introduction

As a result of the German Renewable Energies Act, enacted in 2000, the number and size of biogas plants in Germany has constantly increased. In 2017, more than 9300 biogas plants were operating in Germany with an electrical capacity of P ≈ 4500 ­MWe (German Biogas Association 2017). In 2011, the output of digestate amounted to 65.5 million m­ 3 containing approximately 390,000 t of nitrogen, 74,000 t of phosphorus, and 330,000 t of potassium (Möller and Müller 2012). Raw digestate contains about 1.2–9.1 ­kgN t−1 of total nitrogen with about 44–81% ammonia, 0.4–2.6 k­ gP t−1 phosphorus and 1.2–11.5 ­kgK t−1 potassium (Möller and Müller 2012). Fertilisers based on anaerobic digestion products achieve comparable or even higher biomass

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