Numerical study on pollutant emissions characteristics and chemical and physical exergy analysis in Mild combustion

Abstract

This analytical study appraises the emission characteristics of different pollutants such as CO and NOX as well as conducting chemical and physical exergy analyses on conventional and Mild combustion regimes. The RANS turbulence approach and the k-ε RNG model were utilized in this study to simulate turbulence, whereas the eddy dissipation concept (EDC) model and the GRI–Mech 2.11 chemical mechanism were adopted to treat the turbulence-chemistry interaction. This study evaluated local and global pollutant emissions and exergy efficiency along the reacting jet and explored the effects of temperature and chemical species on the physical and chemical exergies in MILD combustion in comparison to conventional combustion. It is found that the overall exergy efficiency of MILD combustion rises by 1, 3, and 4% for oxygen mass fractions of 3, 6, and 9% in hot oxidizer coflow, with the NOx emissions are 81, 72, and 55% lower than conventional combustion, respectively. Chemical exergy is greater than physical exergy near the fuel nozzle due to high CH4 and H2 concentrations. Chemical exergy reduces along the burner due to chemical reactions, while physical exergy increases due to the increased temperature. However, owing to the trade-off between these two exergies along the flame jet, the total exergy approaches a constant value at large distances from the burner. The maximum total exergy occurs at a distance of 0.12 m from the fuel nozzle, with chemical exergy accounting for 83% of the total exergy. In the outlet (0.5 m from the fuel nozzle), chemical exergy accounts only for 30% of the total exergy. It can also be concluded that the exergy is stabilized at a distance of 0.3 m from the nozzle (60% of the domain length). Despite a higher local CO emission in conventional combustion than in MILD combustion, the CO emission substantially decreases at a smaller distance from the nozzle in conventional combustion due to the high O2 concentration.