Abstract

This study presents the modeling of wood chips pyrolysis, considering the initial moisture content and taking into account the near-parallelepiped geometry of common wood chips, which is not available among the simulated shapes of wood in the literature. The goal is to extend the research and generate useful data on how different varieties of shapes and initial moisture contents influence wood chips pyrolysis. The effects of temperature and thickness variation on the pressure of volatile products, core temperature, and densities of pyrolysis products were studied. The model was validated with the mass fraction of experimental data obtained from beechwood chips with a density of 700 kg/m3 and thickness of 10 mm–30 mm at 973.15 K–1273.15 K. The mean absolute error (MAE) and mean relative error (MRE) values were, respectively, 0.066 and 10.376% at 973.15 K, and 0.065 and 22.632% at 1273.15 K. High temperature favored the rate of biocharcoal production from the surface to the core, though part of the biocharcoal was lost at the surface.

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