Numerical simulation of natural gas-ammonia combustion characteristics in a U-shaped radiant tube

Abstract

NH3, recognized as a carbon-free fuel and a high-energy–density renewable hydrogen carrier, holds promise as a low-carbon alternative fuel. However, its direct combustion is often posed with challenges such as a limited ignition zone and high NOX emissions. To address this, the present paper proposes a strategy to blend more reactive hydrogen-containing fuels with ammonia to enhance combustion stability and concurrently reduce NOX emissions. This study developed numerical models for natural gas-ammonia combustion within a U-shaped radiant tube. The dynamic characteristics of combustion flame flow fields inside the radiation tube were investigated across various mixing ratios, analyzing the effects of nitrogen-containing fuel temperature on NOX generation and elucidating NOX generation patterns under different mixing ratios. The findings indicated that a 30 % NH3 blending ratio in the radiation tube yielded uniform wall temperature distribution along its length, minimal circumferential temperature variation, and an outlet NOX emission of only 20.3 ppm. Furthermore, Pearson correlation coefficient calculations revealed strong correlations between NH3 concentration (0.97), URT temperature (0.88), and NOX generation rate (0.88) within the U-type radiation tube combustion flame and NOX emission content.