Abstract

The true contribution of gas desorption to shale gas production is often overshadowed by the use of adsorption isotherms for desorbed gas calculations on the assumption that both processes are identical under high pressure, high temperature conditions. In this study, three shale samples were used to study the adsorption and desorption isotherms of methane at a temperature of 80 °C, using volumetric method. The resulting isotherms were modeled using the Langmuir model, following the conversion of measured excess amounts to absolute values. All three samples exhibited significant hysteresis between the sorption processes and the desorption isotherms gave lower Langmuir parameters than the corresponding adsorption isotherms. Langmuir volume showed positive correlation with total organic carbon (TOC) content for both sorption processes. A compositional three-dimensional (3D), dual-porosity model was then developed in GEM® (a product of the Computer Modelling Group (CMG) Ltd., Calgary, AB, Canada) to test the effect of the observed hysteresis on shale gas production. For each sample, a base scenario, corresponding to a “no-sorption” case was compared against two other cases; one with adsorption Langmuir parameters (adsorption case) and the other with desorption Langmuir parameters (desorption case). The simulation results showed that while gas production can be significantly under-predicted if gas sorption is not considered, the use of adsorption isotherms in lieu of desorption can lead to over-prediction of gas production performances.

Highlights

  • Gas production from shale rocks has gained attention worldwide due to advances in hydraulic fracturing and multi-lateral drilling technologies [1,2]

  • This agrees with existing literatures on the effect of adsorption on shale gas production [1,2,8,9] and correlates with the total organic carbon (TOC) contents of the samples

  • Such an assumption can lead to a significant over-prediction of gas production depending on the size of the observed hysteresis

Read more

Summary

Introduction

Gas production from shale rocks has gained attention worldwide due to advances in hydraulic fracturing and multi-lateral drilling technologies [1,2]. The word “adsorption” in this context signals a traditional practice of using adsorption isotherms to obtain desorbed gas volumes during gas production calculations [1,2,8,9] This practice is based on the assumption that both sorption processes follow the reversible monolayer adsorption theory underpinning the Langmuir model [10], which is arguably the standard model for shale gas adsorption isotherms [2,11]. This assumption invariably ignores the hysteresis behavior of shale gas adsorption and desorption isotherms at in situ conditions

Objectives
Results
Conclusion
Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call