Abstract

Ultrasonic plasticizing of polymers for micro-injection molding has been proposed and studied for its unique potential in materials and energy-saving. In our previous work, we have demonstrated the characteristics of the interfacial friction heating mechanism in ultrasonic plasticizing of polymer granulates. In this paper, the other important heating mechanism in ultrasonic plasticizing, i.e., viscoelastic heating for amorphous polymer, was studied by both theoretical modeling and experimentation. The influence mechanism of several parameters, such as the initial temperature of the polymer, the ultrasonic frequency, and the ultrasonic amplitude, was investigated. The results from both numerical simulation and experimentation indicate that the heat generation rate of viscoelastic heating can be significantly influenced by the initial temperature of polymer. The glass transition temperature was found to be a significant shifting point in viscoelastic heating. The heat generation rate is relatively low at the beginning and can have a steep increase after reaching glass transition temperature. In comparison with the ultrasonic frequency, the ultrasonic amplitude has much greater influence on the heat generation rate. In light of the quantitative difference in the viscoelastic heating rate, the limitation of the numerical simulation was discussed in the aspect of the assumptions and the applied mathematical models.

Highlights

  • Polymer plasticizing with ultrasonic energy and directly injection molding with ultrasonic sonotrode has been proposed especially for micro-sized parts in fields like electronics, medicine, or biotechnology [1,2,3,4,5]

  • It isthe quite obviousheating that there a distinct transition ofinfluenced the viscoelastic heating rate below and above the glass transition temperature as shown the initial polymer

  • The viscoelastic heating phenomenon of amorphous polymer in ultrasonic plasticization was studied by both theoretical modeling and experimentation

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Summary

Introduction

Polymer plasticizing with ultrasonic energy and directly injection molding with ultrasonic sonotrode has been proposed especially for micro-sized parts in fields like electronics, medicine, or biotechnology [1,2,3,4,5]. In comparison with traditional micro injection molding, over 90% of the polymer can be saved by plasticizing just the small amount of polymer just as required for micro-sized parts [6]. This could be a significant cost factor for micro-molded parts, especially in the case of engineering polymers used for high-performance applications. Another advantage of ultrasonic micro-molding is that external heating for the plasticizing chamber and the mold could be spared due to the propagation of the energetic ultrasound in the molten material [6].

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