Abstract

An anomeric mixture of nucleosides is produced in the fusion of 2,3,4,6-tetra- O-acetyl- d-glucopyranose, and various i- O-substituted derivatives thereof, with 6-benzamidopurine in the presence of certain catalysts. 9-α- d-Glucopyranosyladenine was isolated from the anomeric mixture obtained by the fusion of 2,3,4,6-tetra- O-acetyl- i- O-trichloroacetyl-α- d-glucopyranose with 6-benzamidopurine in the presence of toluene- p-sulphonic acid as catalyst.

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