Abstract
Nucleophilic substitution at the exo-polyhedral boron atoms of claso-decaborate [B10H10]2- in the presence of carbocations, which were generated in situ from various halocarbons (triphe-nylmethyl chloride, 1-bromoadamantan, n-butyl bromide), was studied. The reactions carried out in nucleophilic solvents (cyclic ethers and thioethers, N,N-disubstituted amides, and car-boxylic acids) and in the presence of halocarbons afforded mono-and disubstituted compounds with the exo-polyhedral B—O and B—S bonds, which contained a molecule of the solvent as substituent. The structures of the compounds synthesized were confirmed by the IR, mass, and 1H, 11B, and 13C NMR spectra.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
