Abstract
8-Vinylquinoline and α-methyl-8-vinylquinoline have been prepared in 40–67% overall yield from 8-methyl- and 8-ethyl quinoline, respectively. These unsaturated compounds undergo nucleophilic addition with carbon and oxygen nucleophiles at the terminal vinyl carbon atom in the presence of Pd 11 compounds affording, exclusively, five-membered metallacyclic rings.
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