Abstract
The influence of steric compression on electronic structure in polycyclic olefinic alcohols and amines is studied by PE. spectroscopy.The unsubstituted alcohol 2 and amine 7 show PE.‐spectroscopic properties that can be reconciled by postulating a predominance of intramolecularly H‐bonded species in the gas phase.For the alkylated derivatives 5 and 9, in which H‐bonding is precluded, distinct, but only moderate lone‐pair double‐bond interactions are observed.
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