Abstract

[(η 6-Polyarene)Mn(CO) 3] + complexes containing naphthalene type ligands undergo regioselective nucleophilic addition reactions with H- and C-donors to give moderate to good yields of η 5-cyclohexadienyl complexes. Products derived from hydride addition to naphthalene, phenanthrene and acenaphthene complexes have been characterized by X-ray diffraction.

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