Abstract
High desorption temperature and sluggish desorption kinetics hinder the large-scale application of Mg-based hydrogen storage materials. Fundamental understanding of the dehydrogenation process and underlying mechanism is crucial for further modifying the desorption performance. Aiming at elucidating the dehydrogenation process of Mg-based hydrides, partially desorbed pure MgH2 and MgH2-Mg2NiH4-CeH2.73 composite have been prepared to investigate the effects of metal phase nucleation on overall desorption performance. It is found that metal Mg is formed on the surface of partially desorbed MgH2 and MgH2-Mg2NiH4-CeH2.73. Correspondingly, the desorption temperature of partially desorbed samples is significantly decreased, indicating an important role nucleation plays in desorption process. With minor Ni addition, the desorption temperature and kinetics of MgH2-Mg2NiH4-CeH2.73 are significantly improved. Promoting hydrogen recombination is another essential aspect to modify the desorption properties of Mg hydrides.
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