Abstract
The luminescence of self-trapped excitons in halogen-bridged platinum complexes [Pt(en) 2] [Pt(en) 2X 2](ClO 4) 4 (en=ethylenediamine, X=Br, Cl) has been studied by means of femtosecond up-conversion techniques. The time evolution of the nuclear wave-packet shape is visualized for a Pt–Br system and interpreted in terms of a harmonic-oscillator model.
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