Abstract

Analytical expressions are derived for spin-lattice and spin-spin relaxation times ( T 1M and T 2M) of a nucleus arising from magnetic interactions (dipolar and contact) with a paramagnetic ion which has an anisotropic g tensor. The relaxation rates depend on the orientation of the ion-nucleus vector in the principal-axis system of the g tensor. The deviations caused by this angular dependence with reference to the corresponding relaxation rates for an isotropic g tensor are numerically illustrated by considering a case typical for Co (II) complexes.

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