Abstract

A study is made of nuclear size corrections to the energy levels of single-electron atoms for the ground state of hydrogen like atoms. We consider Fermi charge distribution to the nucleus and calculate atomic energy level shift due to the finite size of the nucleus in the context of perturbation theory. The exact relativistic correction based upon the available analytical calculations is compared to the result of first-order relativistic perturbation theory and the non-relativistic approximation. We find small discrepancies between our perturbative results and those obtained from exact relativistic calculation even for large nuclear charge number Z.

Highlights

  • As we know, the unphysical infinity in the1 r potential at the origin makes it necessary that this potential be modified for values of r inside a region about the origin that can be identified with the nucleus of the atom

  • We can compare the energy eigenvalues derived from equation (9) with the corrected eigenvalues obtained from the first-order perturbation theory under the assumption that the change in the coulomb potential in the interior of the nucleus is treated as a perturbation to the Hamiltonian as, H

  • The dependence of the correction to the energy on the form of the potential energy inside the nucleus necessitates a choice of a model for the nuclear potential

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Summary

Introduction

The unphysical infinity in the r potential at the origin makes it necessary that this potential be modified for values of r inside a region about the origin that can be identified with the nucleus of the atom. The resulting correction due to the finite size of the nucleus leads to the shift of atomic energy levels. The dependence of the correction to the atomic energy level on the form of the potential energy inside the nucleus necessitates a choice of a model for the nuclear potential. For nuclear potential function, which respectively simulate either a uniform charge distribution or a constant potential inside nucleus, the atomic energy level shift has been calculated [1]. Calculation of these type of corrections have attracted a lot of attention. Our numerical results are compared with the results obtained from perturbation theory using both relativistic and non-relativistic wave functions for two physical charge distribution models to the nucleus

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