Abstract

AbstractBy observing the nuclear fluorine‐proton Overhauser effect in aqueous solutions of potassium fluoride it is shown that the longitudinal components of the F19 magnetic moments relax by dipole‐dipole interaction with the protons of the surrounding water molecules and with other fluorine nuclei. The correct method of measuring ionic relaxation times (“double resonance”) leads to relaxation times in these solutions which are slightly different from those obtained by assuming a simple exponential decay of the magnetizations.

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