Abstract
1. Carbon-chain polymers with β-diketone and β-keto ester functional groups in the side chains have been synthesized. 2. The tautomeric equilibrium of the polymeric β-dicarbonyl compounds polymethacryloylacetone and poly(vinyl acetoacetate) and low-molecular models of these polymers has been studied. The effect of the macromolecular nature of the polymeric β-diketones on the tautomeric equilibrium is expressed as a significant difference between their thermodynamic equilibrium parameters and those of the low-molecular analog.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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