Abstract
Several recent NMR relaxation studies in liquids at high pressure are discussed to illustrate the advantages of using pressure as an experimental variable in investigations of the dynamic structure of liquids. The first study deals with the reorientation and angular momentum correlation times in fluorobenzene-d 5. The second study follows the effects of pressure on molecular reorientation in liquid chloroform using analysis of both Raman lineshapes in terms of reorientational correlation functions and corresponding NMR relaxation data. The third study is devoted to the problem of pressure effects on the internal motion of groups within a molecule in the liquid state.
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